» » Zeolite Group

Τρίτη 26 Μαρτίου 2013

Zeolite Group

Zeolite Group.
Show Zeolite Group Photos (10013)
A group name for a large number of framework alumosilicates
(and, rarely, beryllosilicates, zincosilicates, beryllophosphates)
which are built of corner-linked tetrahedra and contain 
exchangeable cations; several of these minerals have important 
technical applications. Several subgroups are distinguished

The current IMA-approved nomenclature is reported in Coombs
et al. (1997).

Note: Tvedalite may also belong to the Zeolite Group (presently uncertain since the crystal structure
of the mineral has not been determined yet).

Other minerals often found associated with zeolites include:

Classification of Zeolite Group

IMA status:Approved 1997
mindat.org URL:http://www.mindat.org/min-4395.html
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Relationship of Zeolite Group to other Species

Group Members:
Alflarsenite
NaCa
2
Be
3
Si
4
O
13
(OH) · 2H
2
O
Amicite
K
2
Na
2
Al
4
Si
4
O
16
· 5H
2
O
Ammonioleucite
(NH
4
,K)(AlSi
2
O
6
)
Analcime
Na
2
(Al
2
Si
4
O
12
) · 2H
2
O
Barrerite
(Na,K,Ca
0.5
)
2
[Al
2
Si
7
O
18
] · 7H
2
O
Bellbergite
(K,Ba,Sr)
2
Sr
2
Ca
2
(Ca,Na)
4
[Al
3
Si
3
O
12
]
6
· 30H
2
O
Bikitaite
LiAlSi
2
O
6
· H
2
O
Boggsite
Ca
8
Na
3
(Si,Al)
96
O
192
· 70H
2
O
Brewsterite
Brewsterite-Ba
(Ba,Sr)[Al
2
Si
6
O
16
] · 5H
2
O
Brewsterite-Sr
(Sr,Ba,Ca)[Al
2
Si
6
O
16
] · 5H
2
O
Chabazite
Chabazite-Ca
(Ca,K
2
,Na
2
)
2
[Al
2
Si
4
O
12
]
2
· 12H
2
O
Chabazite-K
(K
2
,Ca,Na
2
,Sr,Mg)
2
[Al
2
Si
4
O
12
]
2
· 12H
2
O
Chabazite-Levyne Subgroup
Chabazite-Mg
(Mg
0.7
K
0.5
Ca
0.5
Na
0.1
)[Al
3
Si
9
O
24
]·10H
2
O
Chabazite-Na
(Na
2
,K
2
,Ca,Sr,Mg)
2
[Al
2
Si
4
O
12
]
2
· 12H
2
O
Chabazite-Sr
Sr
2
[Al
2
Si
4
O
12
]
2
· 12H
2
O
Chiavennite
CaMnBe
2
Si
5
O
13
(OH)
2
· 2H
2
O
Clinoptilolite-Ca
(Ca,Na,K)
2-3
Al
3
(Al,Si)
2
Si
13
O
36
· 12H
2
O
Clinoptilolite-K
(K,Na,Ca)
2-3
Al
3
(Al,Si)
2
Si
13
O
36
· 12H
2
O
Clinoptilolite-Na
(Na,K,Ca)
2-3
Al
3
(Al,Si)
2
Si
13
O
36
· 12H
2
O
Cowlesite
CaAl
2
Si
3
O
10
· 6H
2
O
Dachiardite-Ca
(Ca,Na
2
,K
2
)
5
Al
10
Si
38
O
96
· 25H
2
O
Dachiardite-Na
(Na
2
,Ca,K
2
)
5
Al
10
Si
38
O
96
· 25H
2
O
Direnzoite
NaK
6
MgCa
2
(Al
13
Si
47
O
120
) · 36H
2
O
Edingtonite
Ba[Al
2
Si
3
O
10
] · 4H
2
O
Epistilbite
CaAl
2
Si
6
O
16
· 5H
2
O
Erionite
Erionite-Ca
(Ca,K
2
,Na
2
)
2
[Al
4
Si
14
O
36
] · 15H
2
O
Erionite-K
(K
2
,Ca,Na
2
)
2
[Al
4
Si
14
O
36
] · 15H
2
O
Erionite-Na
(Na
2
,K
2
,Ca)
2
[Al
4
Si
14
O
36
] · 15H
2
O
Faujasite Subgroup
Faujasite-Ca
(Ca,Na
2
,Mg)
3.5
[Al
7
Si
17
O
48
] · 32H
2
O
Faujasite-Mg
(Mg,Na
2
,Ca)
3.5
[Al
7
Si
17
O
48
] · 32H
2
O
Faujasite-Na
(Na
2
,Ca,Mg)
3.5
[Al
7
Si
17
O
48
] · 32H
2
O
Ferrierite
Ferrierite-K
(K
2
,Na
2
,Mg,Ca)
3-5
Mg[Al
5-7
Si
27.5-31
O
72
] · 18H
2
O
Ferrierite-Mg
(Mg,Na
2
,K
2
,Ca)
3-5
Mg[Al
5-7
Si
27.5-31
O
72
] · 18H
2
O
Ferrierite-Na
(Na
2
,K
2
,Mg,Ca)
3-5
Mg[Al
5-7
Si
27.5-31
O
72
] · 18H
2
O
Flörkeite
(K
3
Ca
2
Na)[Al
8
Si
8
O
32
] · 12H
2
O
Garronite
Na
2
Ca
5
Al
12
Si
20
O
64
· 27H
2
O
Gaultite
Na
4
Zn
2
Si
7
O
18
· 5H
2
O
Gismondine
Gismondine-Ba
Ba
2
Al
4
Si
4
O
16
· 4-6H
2
O
Gismondine-Ca
CaAl
2
Si
2
O
8
· 4H
2
O
Gmelinite
Gmelinite-Ca
(Ca,Na
2
)[Al
2
Si
4
O
12
] · 6H
2
O
Gmelinite-K
(K
2
,Na
2
,Ca)[Al
2
Si
4
O
12
] · 6H
2
O
Gmelinite-Na
(Na
2
,Ca)[Al
2
Si
4
O
12
] · 6H
2
O
Gobbinsite
Na
4
(Ca,Mg,K
2
)Al
6
Si
10
O
32
· 12H
2
O
Gonnardite
(Na,Ca)
2
(Si,Al)
5
O
10
· 3H
2
O
Goosecreekite
Ca[Al
2
Si
6
O
16
] · 5H
2
O
Gottardiite
Na
3
Mg
3
Ca
5
Al
19
Si
117
O
272
· 93H
2
O
Harmotome
(Ba
0.5
,Ca
0.5
,K,Na)
5
[Al
5
Si
11
O
32
] · 12H
2
O
Heulandite-Ba
(Ba,Ca,K,Na,Sr)
5
Al
9
Si
27
O
72
· 22H
2
O
Heulandite-Ca
(Ca,Na)
2-3
Al
3
(Al,Si)
2
Si
13
O
36
· 12H
2
O
Heulandite-K
(K,Na,Ca)
2-3
Al
3
(Al,Si)
2
Si
13
O
36
· 12H
2
O
Heulandite-Na
(Na,Ca)
2-3
Al
3
(Al,Si)
2
Si
13
O
36
· 12H
2
O
Heulandite-Sr
(Sr,Na,Ca)
2-3
Al
3
(Al,Si)
2
Si
13
O
36
· 12H
2
O
Hsianghualite
Ca
3
Li
2
(Be
3
Si
3
O
12
)F
2
Laumontite
CaAl
2
Si
4
O
12
· 4H
2
O
Leucite
K(AlSi
2
O
6
)
Lévyne
Lévyne-Ca
(Ca,Na
2
,K
2
)[Al
2
Si
4
O
12
] · 6H
2
O
Lévyne-Na
(Na
2
,Ca,K
2
)[Al
2
Si
4
O
12
] · 6H
2
O
Lovdarite
(Na,K,Ca)
4
(Be,Al)
2
Si
6
O
16
· 4H
2
O
Maricopaite
Pb
7
Ca
2
(Si,Al)
48
O
100
· 32H
2
O
Mazzite-Mg
K
2
Mg
2
Ca
1.5
Al
9.5
Si
26.5
O
72
· 28H
2
O or near
Mazzite-Na
Na
4
[Al
4
Si
14
O
36
]
2
· 30H
2
O
Merlinoite
(K,Na)
5
(Ca,Ba)
2
Al
9
Si
23
O
64
· 23H
2
O
Mesolite
Na
2
Ca
2
Si
9
Al
6
O
30
· 8H
2
O
Montesommaite
(K,Na)
9
Al
9
Si
23
O
64
· 10H
2
O
Mordenite
(Na
2
,Ca,K
2
)Al
2
Si
10
O
24
· 7H
2
O
Mutinaite
Na
3
Ca
4
Si
85
Al
11
O
192
· 60H
2
O
Nabesite
Na
2
BeSi
4
O
10
· 4H
2
O
Natrolite
Na
2
Al
2
Si
3
O
10
· 2H
2
O
Natrolite Subgroup
Offretite
KCaMgAl
5
Si
13
O
36
· 16H
2
O or near
Pahasapaite
Li
8
(Ca,Li,K)
10.5
Be
24
(PO
4
)
24
· 38H
2
O
Paranatrolite
Na
2
Al
2
Si
3
O
10
· 3H
2
O
Parthéite
CaAl
2
Si
2
O
8
· 2H
2
O
Paulingite
Paulingite-Ca
(Ca,K
2
,Na
2
,Ba)
5
[Al
10
Si
35
O
90
] · 45H
2
O
Paulingite-K
(K
2
,Ca,Na
2
,Ba)
5
[Al
10
Si
35
O
90
] · 45H
2
O
Paulingite-Na
(Na
2
,K
2
,Ca,Ba)
5
[Al
10
Si
35
O
90
] · 45H
2
O
Perlialite
K
9
Na(Ca,Sr)[Al
2
Si
4
O
12
]
6
· 15H
2
O
Phillipsite-Ca
(Ca
0.5
,K,Na,Ba
0.5
)
4-7
[Al
4-7
Si
12-9
O
32
.
12H2O
Phillipsite-K
(K,Na,Ca
0.5
,Ba
0.5
)
4-7
[Al
4-7
Si
12-9
O
32
]
.
12H
2
O
Phillipsite-Na
(Na,K,Ca
0.5
,Ba
0.5
)
4-7
[Al
4-7
Si
12-9
O
32
] · 12H
2
O
Pollucite
(Cs,Na)
2
(Al
2
Si
4
O
12
) · 2H
2
O
Roggianite
Ca
2
Be(OH)
2
Al
2
Si
4
O
13
· 2.5H
2
O
Scolecite
CaAl
2
Si
3
O
10
· 3H
2
O
Stellerite
Ca[Al
2
Si
7
O
18
] · 7H
2
O
Stilbite
Stilbite-Ca
NaCa
4
[Al
9
Si
27
O
72
] · nH
2
O
Stilbite-Na
(Na,Ca,K)
6-7
[Al
8
Si
28
O
72
] · nH
2
O
Terranovaite
(Na,Ca)
8
(Si
68
Al
12
)O
160
· 29H
2
O
Tetranatrolite
Thomsonite-Ca
NaCa
2
[Al
5
Si
5
O
20
] · 6H
2
O
Thomsonite-Sr
Na(Sr,Ca)
2
[Al
5
Si
5
O
20
] · 7H
2
O
Tschernichite
(Ca,Na
2
)[Al
2
Si
4
O
12
] · 4-8H
2
O
Tschörtnerite
Ca
4
(Ca,Sr,K,Ba)
3
Cu
3
[(OH)
2
|Al
3
Si
3
O
12
]
4
· nH
2
O
Wairakite
Ca(Al
2
Si
4
O
12
) · 2H
2
O
Weinebeneite
CaBe
3
(PO
4
)
2
(OH)
2
· 4H
2
O
Wenkite
(Ba,K)
4
(Ca,Na)
6
[(SO
4
)
3
|(Si,Al)
20
O
39
(OH)
2
] · 0.5H
2
O
Willhendersonite
KCa[Al
3
Si
3
O
12
] · 5H
2
O
Yugawaralite
CaAl
2
Si
6
O
16
· 4H
2
O

Other Names for Zeolite Group

Synonyms:
GaargotiZeolite
Other Languages:
German:Kuphit
Zeolith
Simplified Chinese:沸石
Spanish:Zeolita

Other Information

Health Warning:No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

References for Zeolite Group

Reference List:

- +
Taylor, W.H., Meek, C.A., and Jackson, W.W. (1933) The structures of the fibrous zeolites. Zeitschrift für Kristallographie: 84: 373.

Gottardi, G. & E. Galli (1985) Natural Zeolites, 409 p., Springer-Verlag, Berlin.

Tschernich, R. (1992) Zeolites of the world. Geoscience Press Inc., Phoenix, AZ, USA, 563 pp. [freely downloadable:http://www.mindat.org/books/Zeolites-of-the-World-Updated.pdf]

Coombs, D.S., A. Alberti, T. Armbruster, G. Artioli, C. Colella, E. Galli, J.D. Grice, F. Liebau, J.A. Mandarino, H. Minato, E.H. Nickel, E. Passaglia, D.R. Peacor, S. Quartieri, R. Rinaldi, M. Ross, R.A. Sheppard, E. Tillmans & G. Vezzalini (1997) Recommended nomenclature for zeolite minerals: Report of the Subcommittee on Zeolites of the International Mineralogical Association, Commission on New Minerals and Mineral Names. Canadian Mineralogist 35, 1571-1606. [http://www.mineralogicalassociation.ca/doc/abstracts/ima98/ima98(13 [Link Broken? Mar 2013]).pdf ]

Mineralogical Magazine (1998): 62: 533.

Armbruster, T. & M.E. Gunter (2001) Crystal structures of natural zeolites. in D.L. Bish and D.W. Ming, Eds., Natural zeolites: Occurrence, properties, application Reviews in Mineralogy and Geochemistry: 45: 1-57. Mineralogical Soceity of America and Geochemical Society, Washington, USA.

Baerlocher, Ch., Meier, W.M., & Olson, D.H. (2001) Atlas of zeolite framework types, 5th. edition, 302 p. Elsevier, Amsterdam, Netherlands.

Hay, R.L., and R.A. Sheppard (2001) Occurrence of zeolites in sedimentary rocks: An overview. In D.L. Bish and D.W. Ming, Editors, Natural zeolites: properties, applications and uses, 45: 217-232. Reviews in Mineralogy and Geochemistry, Mineralogical Society of America, Chantilly, Virginia.

Lee, Y., T. Vogt, J.A. Hriljac, J.B. Parise, J.C. Hanson & S.J. Kimk (2002) Non-framework cation migration and irreversible pressure-induced hydration in a zeolite: Nature: 420: 485-489.

Vieillard, P. (2010) A predictive model for the entropies and heat capacities of zeolites. European Journal of Mineralogy 22, 823-836.


http://www.iza-online.org

http://icnz.lanl.gov/ [Link Broken? Mar 2013]

http://www.zeolite-collection.eu/

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